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Skylighter.com, great resource for all things pyrotechnic.Plenty of harmless reasons to make your own black powder, thermite, slow match, quick match, pull igniters, electric matches, etc.

They have plenty of articles and project instructions, but be careful, there are a LOT of interesting chemicals and tools, I have a hard time refraining from ordering, even when I am completely broke.

I new kit they should be getting in this summer is a color changing smoke mixture, the video looked pretty good.